```Python
old_dict = {
    "old key": "old value",
    "second old key": "second old value",
}
new_dict = {**old_dict, "new key": "new value"}
```

Here, `new_dict` will contain all the key-value pairs from `old_dict` plus the new key-value pair:

```Python
{
    "old key": "old value",
    "second old key": "second old value",
    "new key": "new value",
}
```